2,2,2-Trichloro-N-(3,4-dimethylphenyl)acetamide
نویسندگان
چکیده
The conformation of the N-H bond in the title compound, C(10)H(10)Cl(3)NO, is anti to the C=O bond. The amide H atom exhibits both intra-molecular N-H⋯Cl and inter-molecular N-H⋯O hydrogen bonding. The latter inter-actions link the mol-ecules into infinite chains.
منابع مشابه
2,2-Dichloro-N-(3,4-dimethylphenyl)acetamide
In the title compound, C(10)H(11)Cl(2)NO, the N-H bond is syn to the 3-methyl substituent in the aromatic ring, similar to that observed in N-(3,4-dimethyl-phen-yl)acetamide and to the 3-chloro substituent in 2,2-dichloro-N-(3,4-dichloro-phen-yl)acetamide, and contrasting with the anti conformation observed for the 3-methyl substituent in 2,2,2-trichloro-N-(3,4-dimethyl-phen-yl)acetamide. On th...
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The crystal structure of the title compound (26DMPCA), C(10)H(12)ClNO, is closely related to those of side-chain-unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain-substituted 2,2,2-trichloro-N-(2,6-dimethyl-phen-yl)-acet-amide and N-(2,6-dimethyl-phen-yl)-2,2,2-trimethylacet-amide, with slightly different bond parameters. The mol-ecules in 26DMPCA are linked into chains through N-H...
متن کامل2,2,2-Trichloro-N-(2,5-dimethylphenyl)acetamide
The N-H bond in the title compound, C(10)H(10)Cl(3)NO, is syn to the 2-methyl and anti to the 5-methyl substituent of the aromatic ring. Adjacent mol-ecules are linked into chains through N-H⋯O hydrogen bonding. Two Cl atoms are each disordered equally over two sites.
متن کاملN-(2,6-Dimethylphenyl)-2-methylacetamide
The structure of the title compound (26DMPMA), C(11)H(15)NO, is closely related to the side-chain unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain substituted N-(2,6-dimethyl-phen-yl)-2,2,2-trimethyl-acetamide and 2-chloro-N-(2,6-dimethyl-phen-yl)acetamide, with slightly different bond parameters. The mol-ecules in 26DMPMA are linked into chains through N-H⋯O hydrogen bonding.
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